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Organophosphorus Compounds, 114. Tetracyclic Phosphorus-Aluminium-Carbon Compounds – Synthesis by Cooligomerization of Kinetically Stabilized Phosphaalkynes with Trialkylaluminium Compounds

✍ Scribed by Hoffmann, Andreas ;Breit, Bernhard ;Regitz, Manfred


Publisher
Wiley (John Wiley & Sons)
Year
1997
Tongue
English
Weight
528 KB
Volume
130
Category
Article
ISSN
0009-2940

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Tricyclic Phosphorus-Carbon Compounds –
✍ Andreas Hoffmann; Andreas Mack; Richard Goddard; Paul Binger; Manfred Regitz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB 👁 1 views

When trialkylaluminum reagents 2 bearing sterically complexes (Ǟ 6a,b), as illustrated by the reactions of 5a with nonacarbonyldiiron or the pentacarbonyltungsten tetra-demanding substituents are allowed to react with phosphaalkynes 1 a highly selective phosphaalkyne hydrofuran complex. When triethy