𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Organophosphorus chemistry. XVII. Kinetics and mechanism of the Perkow reaction

✍ Scribed by Borowitz, Irving J.; Firstenberg, Steven; Borowitz, Grace B.; Schuessler, David

Book ID
120970415
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
719 KB
Volume
94
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Organophosphorus antioxidantsβ€”VIII. Kine
Organophosphorus antioxidantsβ€”VIII. Kinetics and mechanism of the reaction of organic phosphites with peroxyl radicals
✍ K. Schwetlick; J. Pionteck; T. KΓΆnig; W.D. Habicher πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 387 KB

Alrstract--Trialkyl phosphites react with cyanoisopropylperoxyl radicals, generated by thermolysis of azobis(isobutyronitrile) in the presence of oxygen, to give the corresponding phosphates with rate constants of the order of 103 M -~ sec -~ at 65Β°C. Phenyl phosphites are oxidized also. A small amo

Organophosphorus chemistry. 16. The Reac
Organophosphorus chemistry. 16. The Reaction of Furfurylidenemalonitrile with Alkyl Phosphites
✍ Prof. Dr. Wafaa M. Abdou; Maha D. Khidre; Mohamed R. Mahran πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 341 KB

## Abstract Dialkyl phosphites (2a–c) react with furfurylidenemalonitrile (1) to give the corresponding 1:1 phosphonate adducts 3a–c. On the other hand, trialkyl phosphites (6a, b) affected C‐alkylation of the exocyclic ethylenic linkage in compound (1) to give the respective phosphonate 7a, b.