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Organometallic S,S ligands with .pi.-donor properties. Structures and magnetism of bis(cyclopentadienyl)tetrakis(dimethyl monothiophosphito)trinickel [{(C5H5)Ni[P(S)(OCH3)2]2}2Ni], a complex with tetrahedral NiS4 coordination

✍ Scribed by Klaui, Wolfgang; Schmidt, Karin; Bockmann, Anja; Brauer, David J.; Wilke, Jochen; Lueken, Heiko; Elsenhans, Ulrich


Book ID
126992119
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
810 KB
Volume
25
Category
Article
ISSN
0020-1669

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.