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Organometallic reagents in synthesis : A new protocol for construction of the indole nucleus

โœ Scribed by Amos B. Smith III; Melean Visnick; John N. Haseltine; Paul A. Sprengeler

Book ID
108372489
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
794 KB
Volume
42
Category
Article
ISSN
0040-4020

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Naphthalene and related conjugated polycyclic arenes readily coordinate through one carbocyclic ring to Mn(CO) 3 + . The resulting complexes, e.g., ( 6 -naphthalene)Mn(CO) 3 + , function as very effective manganese tricarbonyl transfer (MTT) reagents, largely because of facile 6 โ†’ 4 ring slippage.