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Organometallic reactivity: the role of metal–ligand bond energies from a computational perspective

✍ Scribed by Fey, Natalie; Ridgway, Benjamin M.; Jover, Jesús; McMullin, Claire L.; Harvey, Jeremy N.


Book ID
119976735
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
841 KB
Volume
40
Category
Article
ISSN
1477-9226

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## Abstract Treatment of the complexes [Re(NO)~2~(PR~3~)~2~][BAr^F^~4~] (R = Cy, 1 a; R = __i__Pr, 1 b) with phenyldiazomethane gave the cationic benzylidene species [Re{CH(C~6~H~5~)}(NO)~2~(PR~3~)~2~][BAr^F^~4~] (2 a and 2 b) in good yields. Upon reaction of 2 a and 2 b with acetonitrile, the cons