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Organometallic Polymers of the Transition Metals

✍ Scribed by Alaa S. Abd-El-Aziz


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
875 KB
Volume
23
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

This article provides a comprehensive review of the synthesis, properties and applications of organometallic polymers of the transition metals. The different classes of organometallic polymers are described according to their structural make‐up, as well as by their methods of synthesis. A number of examples of each class are given to emphasize the richness and diversity in these areas of research. In addition to linear polymers, hyperbranched, crosslinked, star and dendritic polymers are also described. The properties that transition metal‐containing organometallic polymers possess, as well as the applications that these materials have found in various domains are highlighted.
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An important series of catalytic reactions involve some of the intermediates and pathways discussed in previous chapters. Alkene metathesis (Eq. 12.1), now gaining wide acceptance in organic and polymer synthesis, goes via metal carbene intermediates. Alkene polymerization, a key modern development