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Organometallic compounds of the lanthanides XCVII. Synthesis and crystal structures of monomeric bis(ethyltetramethylcyclopentadienyl) amide and alkyl derivatives of the lanthanides

✍ Scribed by Herbert Schumann; Esther C.E Rosenthal; Gabriele Kociok-Köhn; Gary A Molander; Jörn Winterfeld


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
695 KB
Volume
496
Category
Article
ISSN
0022-328X

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The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4