Organometallic compounds in organic synthesis—part 17: Reactions of tricarbonylcyclohexadienyliron salts with o-silylated enolates, allyl silanes and aspects of their synthetic equivalents

Organometallic compounds in organic synt

Organometallic compounds in organic synthesis. An equivalent of aromatic nucleophilic substitution by reactions of tricarbonylcyclohexadienyliumiron salts with O-silylated enolates: a novel arylation in the 2-position of carbonyl compounds.

✍ Lawrence F. Kelly; Acharan S. Narula; Arthur J. Birch 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 255 KB

surmnary: TricarbonylcycZohexudienyZiwniron sdts are synthetGaZZy equivaZent to specifieuZZy suhtituted phenyE cationa. More extensive ability to form carbon-carbon bonds with aromatic rings would enlarge the scope of useful synthetic methods.1 Nucleophilic substitution of aryl halides by carbon nuc