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Organometallic complexes with metal-metal bonds : XII. A trimetallic carbene complex with MoPtMo bonds. Preparation and structure of trans-Pt(C6H11NC)(C6H11NHCOC2H5[Mo(CO)3-η5-C5H5]2

✍ Scribed by Pierre Braunstein; Egbert Keller; Heinrich Vahrenkamp

Book ID
108354429
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
642 KB
Volume
165
Category
Article
ISSN
0022-328X

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## Abstract Reactions of one or two equiv. of cyclohexyl isocyanide in THF at room temperature with MoMo triply bonded complexes [Mo(CO)~2~(__η__^5^‐C~5~H~4~R)]~2~ (R=COCH~3~, CO~2~CH~3~) gave the isocyanide coordinated MoMo singly bonded complexes with functionally substituted cyclopentadienyl l