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Organometallic CN coupling between N,N′-dichloro-p-benzoquinone diimine and Grignard reagents and its application to synthesis of polyanilines

✍ Scribed by Takakazu Yamamoto; Ismayil Nurulla; Asako Ushiro

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
133 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

A new C-N coupling reaction between N,N%-dichloro-p-benzoquinone diimines and aryl Grignard reagents has been developed. The new method gives N,N%-diaryl-p-benzoquinone diimines in 50-88% isolated yield. The obtained new compounds are regarded as oligomeric model compounds for pernigraniline-type polyaniline, and their chemical behavior has been investigated. New polyaniline-type polymers have been prepared by applying the developed C-N coupling reaction.

📜 SIMILAR VOLUMES

ChemInform Abstract: Organometallic C—N
ChemInform Abstract: Organometallic C—N Coupling Between N,N′-Dichloro-p-benzoquinone Diimine and Grignard Reagents and Its Application to Synthesis of Polyanilines.
✍ Takakazu Yamamoto; Ismayil Nurulla; Asako Ushiro 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 25 KB 👁 2 views

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