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Organometallic chemistry of carbon-nitrogen multiple bonds. 2. Reactions of cyclopentadienyldicarbonyliron anion with iminium salts; chemistry of the products

✍ Scribed by Barefield, E. Kent; Sepelak, D. J.


Book ID
126271129
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
1019 KB
Volume
101
Category
Article
ISSN
0002-7863

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Improvements in the synthesis of g-bromo-difluoromethanimine, CF2=NBr. will be described along with some reaction chemistry. The imine undergoes thermal addition with a variety of olefins, leading to the simple addition product and to the formation of telomers. Photolysis with CO forms the isocyanat