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Organolithium additions to styrene derivatives: Intramolecular alkylation processes

✍ Scribed by Xudong Wei; Richard J.K. Taylor

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
105 KB
Volume
37
Category
Article
ISSN
0040-4039

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Organolithium addition to styrene and its derivatives, followed by electrophilic trapping, has been investigated in the presence of (-)-sparteine. With styrene, enantiomeric excesses up to 30% were observed, the ee depending on the solvent, temperature and electrophile. With 2-substituted styrenes,

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