✦ LIBER ✦
Organolithiens a structure “cage” reactivite vis-a-vis des cetones non enolisables coexistence d'un complexe evolutif et d'un complexe inerte
✍ Scribed by D Lozach; G Molle; P Bauer; J.E Dubois
- Book ID
- 104221624
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 193 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The dark orange color produced by the condensation of an excess of lithium compound IV with ketone II was monitored by U.V. and stopped flow spectroscopy. This coloring was ascri-Gd to a Lithiumcompound-ketone complex which evolves into condensation alcohol V. In determining the reaction products we detect the existence of a second inert complex which, when hydro-Lized, releases the initial ketone.