Organogermanium compounds. V. Electron spin resonance study of alkyl- and aryl-substituted germyl radicals
โ Scribed by Sakurai, Hideki; Mochida, Kunio; Kira, Mitsuo
- Book ID
- 127307716
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 372 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The electron spin resonance spectra of the tris(4-nitrophenyl)methyl and tris(2,3,5,6-tetrafluoro-4-nitro-pheny1)methyl radicals in toluene solution have been obtained and their "N, ' % and 'H hypefine splitting constants have been determined. Analysis of the data indicates that fluorine substituent
The role of alkyl substitution on the electronic structure of cyclohexane radical cation was investigated with low-temperature matrix ESR and semiempirical MO calculations. It was found that the unpaired electron, which is originally delocalized throughout the cyclohexane ring, tends to be confined
Electron spin resonance (ESR) and electron nuclear double resonance (ENDOR) measurements were performed for the cation radicals obtained from the model compounds of c~-, #-, 3'and 6-tocopherol (vitamin E) by oxidizing the tocopherol precursors in an AICI3-CHaCI a solution. The proton hyperfine coupl