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Organocatalyzed Asymmetric α-Aminoxylation of Aldehydes and Ketones—An Efficient Access to Enantiomerically Pure α-Hydroxycarbonyl Compounds, Diols, and Even Amino Alcohols

✍ Scribed by Pedro Merino; Tomas Tejero


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
110 KB
Volume
43
Category
Article
ISSN
0044-8249

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✦ Synopsis


Scheme 3. Enantioselective (S)-proline-catalyzed a-aminoxylation of aldehydes. TIPS = triisopropylsilyl. [16] Scheme 4. Catalytic cycle for the (S)-proline-catalyzed a-aminoxylation of carbonyl compounds.