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Organocatalytic asymmetric Michael reaction with acylsilane donors

✍ Scribed by Wu, Lei ;Li, Guangxun ;Fu, Qingquan ;Yu, Luoting ;Tang, Zhuo

Book ID
118071005
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
448 KB
Volume
11
Category
Article
ISSN
1477-0520

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✍ Kwang-Su Choi; Sung-Gon Kim 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 463 KB

## Abstract A catalytic enantioselective Michael addition–cyclization reaction of nitroalkanes with __o__‐hydroxycinnamaldehydes has been established by using a diphenylprolinol TMS ether as an organocatalyst. The reaction afforded the corresponding 4‐substituted chroman‐2‐ols in excellent yields w