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Organocatalytic asymmetric epoxidation reactions in water–alcohol solutions

✍ Scribed by Zhuang, Wei; Marigo, Mauro; Jørgensen, Karl Anker

Book ID
120814158
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
89 KB
Volume
3
Category
Article
ISSN
1477-0520

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Organocatalytic asymmetric syn-selective direct aldol reactions in water
✍ Yong-Chua Teo; Guan-Leong Chua; Chin-Yee Ong; Chai-Yun Poh 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 543 KB

A practical and convenient organocatalytic strategy is developed to provide a direct route to syn-selective aldol products in the presence of water. The siloxy serine organocatalyst mediates the direct aldol reaction of TBSO-protected hydroxyacetone with a variety of aldehydes to provide the aldol p