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Organocatalytic Asymmetric Epoxidation of Olefins by Chiral Ketones

โœ Scribed by Shi, Yian


Book ID
118118184
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
544 KB
Volume
37
Category
Article
ISSN
0001-4842

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Chiral ketones 1 and 2 bearing 1-aza-7-oxabicyclo[3.5.0]decane skeleton and their C 2 -symmetric analogue 3 were readily prepared and evaluated as a chiral dioxirane precursor for asymmetric epoxidation of olefins with Oxone ยฎ . The ketone 2, bearing a diphenyl steric wall, was not effective and gav

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