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Organoboron Compounds. IV. Reaction of Tri-n-butylborine with Peroxides and with Oxygen. Mechanism of Autoöxidation

✍ Scribed by Johnson, John R.; Campen, M. G. Van

Book ID
120825169
Publisher
American Chemical Society
Year
1938
Tongue
English
Weight
484 KB
Volume
60
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

The free-radical reaction of tri-n-butyl
The free-radical reaction of tri-n-butyltin hydride with peroxides
✍ J. L. Brokenshire; K. U. Ingold 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 744 KB

## Abstract Rate constants for the tri‐__n__‐butyltin radical (**Sn ·**) induced decomposition of a number of peroxides have been measured in benzene at 10°C. The values range from ∼100 __M__^−1^ sec^−1^ for di‐__t__‐butyl peroxide to 2.6 × 10^7^ __M__^−1^ sec^−1^ for di‐__t__‐butyl diperoxyisophth