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Organoboron compounds: CDXI. Synthesis of 2-substituted 1-iodo-4-hydroxymethyl-1,6-heptadienes from 1-bora-2-cyclohexene compounds

✍ Scribed by B.M. Mikhailov; L.I. Lavrinovich


Book ID
103224697
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
336 KB
Volume
264
Category
Article
ISSN
0022-328X

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## Abstract A facile method for the synthesis of substituted 3‐(2‐furylidene)‐2‐furanones has been developed using cyclofunctionalization reactions of 2,4‐dialkenyl‐1,3‐dicarbonyl compounds and iodine as electrophile in the presence of Na~2~CO~3~, in refluxing chloroform. Compounds 4 are obtained i