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Organoboranes: XXVIII. Convenient procedures for the synthesis of borinane

✍ Scribed by Herbert C. Brown; Ganesh G. Pai


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
648 KB
Volume
250
Category
Article
ISSN
0022-328X

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A convenient procedure for the synthesis
✍ Kung K. Wang; Zhongguo Wang πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 332 KB

Bromoboration of l-hexyne with BBr, followed by treatment with 2-propanol produced alkenyl boronic ester 3. Subsequent Pd(O)-catalyzed cross-coupling with acetylenic zinc chlorides and iodination furnished enyne iodides 6, which were then converted to enyne-allenes 8 by a second Pd(O)-catalyzed reac