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Organoaluminum-phosphine chemistry. Synthesis and molecular structure of [Ph2P(O)2 · AlCl2]2 and [Ph2P · Al(i-Bu)2]2

✍ Scribed by Samuel A. Sangokoya; William T. Pennington; Gregory H. Robinson; Duane C. Hrncir


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
677 KB
Volume
385
Category
Article
ISSN
0022-328X

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Reaction of cupferron [NH 4 L, L = PhN(O)NO -] with tin(IV), complex 2. The tin centers are heptacoordinated in a pentagonal bipyramidal geometry in the dimeric complex 3. diphenyltin(IV) and dimethyltin(IV) halides yields the cupferronato complexes SnL 4 (1), Ph 2 SnL 2 (2) and These complexes inco