Organische Phosphorverbindungen VIII. Di
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Ludwig Maier
📂
Article
📅
1963
🏛
John Wiley and Sons
🌐
German
⚖ 934 KB
The attack of an oxy radical (produced by the hypoiodite reaction) on a tertiary hydrogen atom, followed by base treatment, leads to an allylic ether: a 4u-hydroxy-5pH-steroid gives a ~l~~-4cr,9u-oxide as the main reaction product. It is postulated, that in cases where the initial 1,5-hydrogen shift