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Organische Phosphorverbindungen. XXVII Die direkte Synthese von Tetramethylphosphoniumhalogeniden

✍ Scribed by Ludwig Maier


Publisher
John Wiley and Sons
Year
1966
Tongue
German
Weight
449 KB
Volume
49
Category
Article
ISSN
0018-019X

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📜 SIMILAR VOLUMES


Organische Phosphorverbindungen VIII. Di
✍ Ludwig Maier 📂 Article 📅 1963 🏛 John Wiley and Sons 🌐 German ⚖ 934 KB

The attack of an oxy radical (produced by the hypoiodite reaction) on a tertiary hydrogen atom, followed by base treatment, leads to an allylic ether: a 4u-hydroxy-5pH-steroid gives a ~l~~-4cr,9u-oxide as the main reaction product. It is postulated, that in cases where the initial 1,5-hydrogen shift