✦ LIBER ✦

Organic–inorganic hybrid material. I. Synthesis, characterization, and thermal property of a novel polyhedral cubic silsesquioxane

✍ Scribed by Enock O. Dare; Gabriel A. Olatunji; David S. Ogunniyi

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 120 KB
Volume: 93
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.20530

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✦ Synopsis

Abstract

Hydrosilylation of 2‐chloroethylvinyl ether by octahydridosilsesilsesquioxane catalyzed by hexachloroplatinic acid was carried out to afford a quantitative yield of 3 in its white crystals. Thermogravimetric analysis of Si~8~O~12~(CH~2~CH~2~OCH~2~CH~2~Cl)~8~ 3 revealed that it is reasonably thermally stable. Spectroscopic data and crystal structure were used to justify the integrity, structural and molecular connectivity of the hitherto novel compound. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 907–910, 2004

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