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“Organically Solvated” Magnesium for the Synthesis of Transition-Metal Complexes and Catalysts

✍ Scribed by Prof. Dr. Helmut Bönnemann; Prof. Dr. Borislav Bogdanović; Rainer Brinkmann; Da-Wei He; Bernd Spliethoff


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
138 KB
Volume
22
Category
Article
ISSN
0044-8249

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Carbonylation of Transition-Metal Carbyn
✍ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 2 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and −30°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60°C and under 60atm pre