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Organic syntheses with sulfones noxxxvi: conversion of sulfones into aldehydes and ketones.

✍ Scribed by J.-B. Baudin; M. Julia; C. Rolando


Book ID
104226951
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
142 KB
Volume
26
Category
Article
ISSN
0040-4039

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Addition of the carbanion of chloromethyl methyl sulfone to aldehydes and ketones proceeds faster than its degradation via the Ramberg-Baecklund reaction. Chlorohydrins and oxiranes produced from aldehydes treated with an excess of base undergo the Ramberg-Baecklund reaction giving allylic alcohols,