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Organic sonochemistry. Ultrasound promoted coupling of chlorosilanes in the presence of lithium wire

✍ Scribed by Philip Boudjouk; Byung Hee Han

Book ID: 104242505
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 106 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91315-2

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✦ Synopsis

Triorganometal chlorides, R3MCl (R = alkyl, aryl; M = Si, Sn) are readily coupled to form bimetallics in 42-95% yields using Li wire and ultrasound.

Dihalosilanes give good yields of cyclic polysilanes.

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