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Organic Reactions Under High Pressure. IX. Some Observations on the Decomposition of Diacyl Peroxides 1

โœ Scribed by Walling, Cheves; Moulden, Howard N.; Waters, James H.; Neuman, Robert C.


Book ID
127181246
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
481 KB
Volume
87
Category
Article
ISSN
0002-7863

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Organic reactions under high pressure. I
โœ Walling, Cheves ;Tanner, Dennis D. ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 304 KB

## Abstract The radical polymerization of methyl methacrylate has been carried out at 51ยฐC. over a pressure range of 1โ€“8000 kg./cm.^2^, and the stereochemistry of the polymer analyzed by NMR spectroscopy. Over the entire pressure range, the stereochemistry of addition is independent of the stereoch