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Organic reactions mediated by electrochemically generated ArS+

โœ Scribed by Matsumoto, Kouichi; Suga, Seiji; Yoshida, Jun-ichi


Book ID
118215729
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
876 KB
Volume
9
Category
Article
ISSN
1477-0520

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Vitamin B 12 enzymes, involving the cobalt species as a catalytic center, mediate various isomerization reactions accompanied by carbon-skeleton rearrangements. In order to simulate the catalytic functions of vitamin B 12 as exerted in the hydrophobic active sites of enzymes concerned, we have been