✍ Scribed by Knipe, A. C.
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A Ab initio calculations β-(acetoxy)vinyl radical rearrangements 505 acyl radical/imine additions 12 CASSCF AND CASPT2, for 3-vinylmethylenecyclobutane rearrangement 503 diethylzinc/aldehyde addition 28 metadynamics, formamide hydrolysis 60 β-(nitroxy)vinyl radical rearrangements 505 QM/MM free energy, phosphate monoester reactions 79 reductive amination 41 on S N 2 reactions 236 unimolecular elimination reactions 309 Abstraction, hydride 41 Acemethacin 75-6 Acetaldehyde-d 1 , oxidation of 92 Acetalization, terminal alkene 330 Acetals 2-3 formation 191 Acetates, substitution reactions 233 Acetic anhydride acylation of 59 in choline acetylation 71 Acetophenones, chalcones from 362 Acetophenoximes, oxidation of 100 Acetoxy group, 1,2-rearrangements, vinyl radicals 507 β-(Acetoxy)vinyl radicals, rearrangements 505 Acetylacetone Michael addition of 356 oxidation of 95 N-Acetylated 2,4,5-triphenylimidazolinium salts 464 Acetylation of p-t-butyl[3.1.3.1]homooxacalixarene 453 of choline, with Ac 2 O 71 Acetylcholine 71 N-Acetylcysteamine, addition of 341 N-Acetyl-l-cysteine, addition of 341 2-Acetyl-1-hydroxyanthraquinone esters 453 N 2 -Acetyl-l-lysine, addition of 341 1-Acetylvinyl acrylates reaction with furan 196 reaction with thiophene 196 Achmatowicz rearrangements 498 Acid anhydrides 58-9 Acid catalysis hydrolysis, formamide, KIE studies 59 rearrangements, tricyclo-[4.2.2.2 2,5 ]dodeca-3,7,9,11-tetraene 463 Acid halides 58-9 Acid hydrolysis acemethacin 76 1-azabicyclo[2.2.2]octan-2-one 77 indomethacin 76 3-methyl-δ-valerolactam 77 Acidity, thioamide 15 and hydrogenation 39 Acids, α,β-unsaturated, oxidation of 102 Acrolein, addition to 347 Acrylonitriles, substituted, formation of 329 Activated aromatics, iodination with 188 Activated bleomycin, oxidation with 101 Activation energy aziridine ring opening 246 lack of, 16 O-18 O isomerization 267 t-BuFH + S N reactions 265 THF formation 268 Activation parameters aldehyde oxidation 42
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