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Organic reaction in water. Part 3: A facile method for reduction of aromatic rings using a raney Ni–Al alloy in dilute aqueous alkaline solution under mild conditions

✍ Scribed by Takehito Tsukinoki; Tadashige Kanda; Guo-Bin Liu; Hirohisa Tsuzuki; Masashi Tashiro *

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
151 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reduction of aromatic rings such as phenol, naphthalenes, biphenyls, acenaphthene, and acenaphthylene was smoothly performed using a Raney Ni±Al alloy in dilute aqueous alkaline solution without any organic solvents at 90 C under atmospheric pressure, and the corresponding reduced compounds were obtained in high yields.

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Organic reaction in water. Part 2. A new
Organic reaction in water. Part 2. A new method for dechlorination of chlorobiphenyls using a Raney NiAl alloy in dilute aqueous alkaline solution
✍ Guo-Bin Liu; Takehito Tsukinoki; Tadashige Kanda; Yoshiharu Mitoma; Masashi Tash 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 193 KB

Use of a Rane~ Ni-AI allo~ in dilute aqueous alkaline solution gave rise to strong reducing l',¢)wer and chlorobiphen~.ls ~ere reduced easil~ to biphenyl and/or phen5 Icyclohexane, respectivel,,., without an~' orqanic solvent~.