✦ LIBER ✦

Organic radicals based on phenalenyl and verdazyl units

✍ Scribed by Yanhui Hou; Huikai Wang; Zhi Li; Yongsheng Liu; Xiangjian Wan; Xiaosong Xue; Yongsheng Chen; Ao Yu

Publisher: Elsevier Science
Year: 2011
Tongue: French
Weight: 564 KB
Volume: 52
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2011.05.031

No coin nor oath required. For personal study only.

✦ Synopsis

Stable phenalenyl (PLY) radicals without sterically bulky substituents need to be synthesized for application as neutral organic molecular conductors. Verdazyl radicals, which have high stability even without sterically bulky substituents, were combined with PLY radicals to produce two novel radicals. The stability of the dimethylthiourea substituted PLY radical is supported by the experimental results and quantum chemical calculations.

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