Organic photochemistry with 6.7eV photons: decomposition of 1,1-disubstituted cyclopropanes in solution

✍ Scribed by R. Srinivasan; Thomas Baum; Jose A. Ors

• Book ID: 104243462
• Publisher: Elsevier Science
• Year: 1981
• Tongue: French
• Weight: 177 KB
• Volume: 22
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)92345-7

✦ Synopsis

The course of the two-bond cleavage reactions of cyclopropanes in photolysts at 185nm in solutton IS strtkmgly mfluenced by dtsubstttution of one of the carbons m the rmg Photodecomposttion of alkyl substttuted cyclopropanes in solution with 185nm radiatton has been shown to lead to both one-and two-bond cleavage 2-4 The former reaction (Eq. 1) whtch IS hr 1x5