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Organic Peroxides. XXI. A Study of the Decomposition of 2,5-Dimethyl-3-hexyn-2,5-Dihydroperoxide 1

โœ Scribed by Milas, Nicholas A.; Nolan, John T.


Book ID
126135405
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
647 KB
Volume
80
Category
Article
ISSN
0002-7863

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Stereoisomeric 2,5-Dimethyl-2,3:4,5-diox
โœ Dr. G. Bernhardt; Prof. Dr. F. Korte ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 237 KB ๐Ÿ‘ 1 views

The [Co(PF3)4]0 anion can be precipitated from aqueous solutions with voluminous cations. During the conversion of HCo(PF3)d into [Co(PF3)4]0, a bathochroniic shift of the P-F valence vibrations is observed which is probably due to a reduction in the double-bond character of the P-F bond. At PF3-pr