Organic Nanoparticles with Polypropyleneoxide Chains as Support for Metallocene Catalysts: Ethylene Homopolymerization and Ethylene/α-olefin Copolymerization
✍ Scribed by Yong-Jun Jang; Nikolay Nenov; Markus Klapper; Klaus Müllen
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 889 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0170-0839
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Copolymerization of ethylene with higher a-olefins, such as 4-methyl-1-pentene, 1-hexene, 1-octene and 1-dodecene, was carried out with both aspecific and isospecific bridged metallocene complexes, comparing the catalytic behaviour Ž . following metallocene supportation on methylalumoxane-pretreated
Metallocene and other single-site catalysts can be combined to produce polyolefins with broadened distributions of molecular weight, chemical composition, and long-chain branching. These resins are finding increasing applications because of their enhanced properties compared to ones made with conven