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Organic metals: ET cation-radical salts with tetrahedral BF4− and HSO4− anions

✍ Scribed by Kushch, N.D.; Yagubskii, E.B.; Korotkov, V.E.; Shibaeva, R.P.; Buravov, L.I.; Zvarykina, A.V.; Laukhin, V.N.; Khomenko, A.G.

Book ID
122792518
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
159 KB
Volume
42
Category
Article
ISSN
0379-6779

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Syntheses, crystal structures and Raman
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In the system BaF 2 /BF 3 /PF 5 /anhydrous hydrogen fluoride (aHF) a compound Ba(BF 4 )(PF 6 ) was isolated and characterized by Raman spectroscopy and X-ray diffraction on the single crystal. Ba(BF 4 )(PF 6 ) crystallizes in a hexagonal P62m space group with a ¼ 10.2251(4) Å, c ¼ 6.1535(4) Å, V ¼ 5

ChemInform Abstract: Syntheses, Crystal
ChemInform Abstract: Syntheses, Crystal Structures and Raman Spectra of Ba(BF4)(PF6), Ba(BF4)(AsF6) and Ba2(BF4)2(AsF6) (H3F4). The First Examples of Metal Salts Containing Simultaneously Tetrahedral BF-4 and Octahedral AF-6 Anions.
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