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Ordering and segregation reactions in b.c.c. binary alloys

✍ Scribed by Gerhard Inden


Publisher
Elsevier Science
Year
1974
Weight
876 KB
Volume
22
Category
Article
ISSN
0001-6160

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✦ Synopsis


Within the Bragg-Williams-Gorsky approximation the most stable atomic configuration3 of b.c.c. solid 3olution3 will be determined in dependence on two energy parameters 11'7"' and W'"', the interchange energies between nearest and next-nearest neighbors. The most stable atomic configuration3 of homogeneou3 solid solution3 (configuration diagrams) are presented for a representative 3et of values out of the whole range of W1 and W (*I. From these results the most stable states of solid solutions, if heterogeneous concentration distributions are permitted (in the pha3e diagrams), are determined. REACTIOSS D'ORDRE ET DE SEGREGATIOS D-ASS DES ALLIAGES BISAIRES CGBIQL-ES CESTRES Dan3 l'approximation de Bragg-William+Gorsky les configurations atomiques les plus stable3 ont et& determinees pour de3 alliages binaires cubiques cent& en fonction de deux parametres Bnerge. tiques Wr' et W2' repr63entant les energie3 d'echange entre premier3 et 3econds voisina. Pour un choir repre3entatif de valeurs de ces parametres les configuration3 le3 plus atables d'alliages homogenes ont et6 determin6es (diagramme de configuration). A partir de ce3 resultat les &at3 lee plus stable3 de3 alliages 3an3 re3triction d'homogeneite (diagrammes de phases) ont et& cleduit3. ORDSUSGS-T_XD ESTMISCHUXGSRE_~KTIOSES IS K.R.Z. BIS:iRE?r' LEGIERUXGES Die stabilsten _1ltomanordnungen in k.r.z. Mischkri3tallen werden in der Bragg-Williams-Gorsky Saherung in Abhangigkeit van zwei Energieparametern W") und W*', den Austauschenergien zwi3chen nachsten und iibernachsten Sachbarn, ermittelt. Fur eine reprasentative Auswahl fiir 1V"' und W2' au3 dem gesamten Wertebereich werden die stabilsten dtomanordnungen fiir homogene Mischkristalle (Konflgurationsdiagramme) dargestellt. Mit Hilfe dieser Ergebni33e werden die stabilsten Yischkristallzustilnde, rrenn heterogene Konzentrationsverteilungen zugelassen 3ind (ZustandJdiagramme), bestimmt.


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Decomposition and ordering processes in b.c.c. binary alloys are calculated by a pairwise interaction model. The interaction energy includes two terms due to a negative interchange energy V between the 1st neighbouring atoms which represents the ordering tendency and due to a positive interchange en