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Order-disorder phenomena in vanadium phosphates. Structures and properties of tetragonal and monoclinic VPO4(H2O)

โœ Scribed by A. El Badraoui; J.Y. Pivan; M. Maunaye; O. Pena; M. Louer; D. Louer


Book ID
114124661
Publisher
Editions Lavoisier
Year
1998
Tongue
English
Weight
230 KB
Volume
23
Category
Article
ISSN
0151-9107

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The solution-phase synthesis, single crystal structure, and some physical properties of CN 3 H 6 โ€ข VO(H 2 O)(HPO 4 ) (H 2 PO 4 ) โ€ข H 2 O, a new guanidinium vanadium (IV) hydrogen phosphate hydrate, are reported. This phase is built up from one-dimensional chains of VO 5 (H 2 O) octahedra and (H 2 /H