Order and disorder in lithium tetrahydroborate
β Scribed by Samantha K. Callear; E. Anne Nickels; Martin O. Jones; Motoaki Matsuo; Shin-Ichi Orimo; Peter P. Edwards; William I. F. David
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 276 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-2461
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π SIMILAR VOLUMES
A vibrational satellite of the rotational spectrum of lithium tetrahydroborate LiBH 4 , which was assigned to the first excited torsional state of the BH 4 group, showed two types of anomalies, and they were explained by the interaction of the torsional motion with the overall rotation. The first an
## Abstract Lithiumβ7 and lithiumβ6 spectra were obtained for four solid airβsensitive complexes of LiBH~4~ under both magic angle spinning (MAS) and static conditions. The MAS experiments were carried out using a specially designed rotor insert to prevent degradation of the sample. The spectra yie
1:1) / Lithium tetrahydridoborate dimethoxyethane (1:2) / Lithium tetrahydridoborate triglyme (1:1) / Lithium tetrahydridoborate tetrahydrofuran (1:3) / Lithiumtetrahydridoborate 1,3-dioxolane (1:1) / Hydridebridge bonding LiBH 4 β’ OEt 2 (1) and LiBH 4 β’ O(Me)CMe 3 (2) form double-centers through tw