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Orbitally dependent magnetic coupling between cobalt(II) ions: The problem of the magnetic anisotropy

✍ Scribed by Palii, Andrei V.; Tsukerblat, Boris S.; Coronado, Eugenio; Clemente-Juan, Juan M.; Borrás-Almenar, Juan J.


Book ID
121723384
Publisher
American Institute of Physics
Year
2003
Tongue
English
Weight
403 KB
Volume
118
Category
Article
ISSN
0021-9606

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Magnetic Exchange between Orbitally Dege
✍ J.J. Borrás-Almenar; E. Coronado; J.M. Clemente-Juan; A.V. Palii; B.S. Tsukerbla 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 545 KB

In this paper we show that a strong magnetic anisotropy appears in exchange mixed+valence clusters containing orbitally degenerate metal ions. Combining an e4ective Hamiltonian approach with the technique of the irreducible tensor operators (ITO) and pseudoangular momentum representation we have sol