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Orbital symmetry conservation and frontier orbital control in the reactions of organic radical cations

✍ Scribed by Ian R. Dunkin; Lester Andrews


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
847 KB
Volume
41
Category
Article
ISSN
0040-4020

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Unimolecular chemistry of oxazole and is
✍ R. Flammang; M. Plisnier; G. Bouchoux; Y. Hoppilliard; S. Humbert; C. Wentrup πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 837 KB

Molecular radical cations of oxazole (1) and isoxazole (2) dissociate by losing carbon monoxide or a hydrogen atom, respectively. These fragmentations were examined by use of tandem mass spectrometry, flash vacuum pyro- lysis and ab initiu molecular orbital calculations. A multi-step mechanism is pr