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Orbital overlap constraints in the thermal rearrangement of 3,7-dimethylenetricyclo[4.1.0.02,4]heptane derivatives

✍ Scribed by Wendt, Michael D.; Berson, Jerome A.


Book ID
126880198
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
959 KB
Volume
115
Category
Article
ISSN
0002-7863

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✍ Hendrik Disteldorf; Jens Renner; Heinrich Heydt; Paul Binger; Manfred Regitz 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

## Abstract 1,5,8‐Triphosphaisolumibullvalenes (1,5,8‐triphosphatetracyclo[4.4.0.0^2,8^.0^5,7^]deca‐3,9‐dienes) **3**, when suitably substituted, undergo thermal rearrangement to afford the 1,1b,2a‐triphosphahomoquadricyclanes (tetrahydro‐1__H__‐1,1b,2a‐triphosphadicyclopropa[__cd__,__gh__]‐pentale