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Optimum geometry of CO dimer and FT-IR spectra of CO in solid argon

✍ Scribed by Hyouk Soo Han; Kwan Kim

Book ID
114142526
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
862 KB
Volume
418
Category
Article
ISSN
0166-1280

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✍ Amanda Horton-Mastin; Martyn Poliakoff πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 575 KB

High-resolution FT-IR spectra (resolution 0.06 cm-') of Cr("C0)6 isolated in Ar matrices at 10 K show that the tro C-O stretching mode gives rise to three closely spaced bands. The spectrum of matrix-isolated Cr('2CO)5('3CO) provides sufficient additional information to produce a quantitative model