✦ LIBER ✦
Optimized Batchwise and Continuous Microreactor Synthesis of a (Bathophenanthroline)ruthenium(II) Complex Carrying Different Ligands
✍ Scribed by Rolf A. Kramer; Luigi Rumi; Willi Bannwarth
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- German
- Weight
- 254 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
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By changing the Ru‐source, the reaction conditions, and the workup/purification procedure, the batchwise synthesis of a mixed [Ru^II^(bathophenanthroline)] complex, i.e., of 4b, could substantially be improved (bathophenanthroline=4,7‐diphenyl‐1,10‐phenanthroline). In addition, we were able to adapt both steps of the synthesis to a microreactor system leading to the desired Ru‐complex in a continuous preparation in very high yields. The latter approach is especially suited for an envisaged scale‐up.