Optimized access to alkyl thiocyanates
✍ Scribed by Pierre-Yves Renard; Hervé Schwebel; Philippe Vayron; Eric Leclerc; Sonia Dias; Charles Mioskowski
- Book ID
- 104231893
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 111 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Functionalized alkyl thiocyanates are synthesized in high yields from corresponding halides via in situ formation of tetra n-butylammonium thiocyanate. Use of this mild but efficient thiocyanation reagent limits the amounts of by-products.
📜 SIMILAR VOLUMES
Aldehydes R F (CH 2 ) m CHO (R F =n-C n F 2n+1 ) have been prepared in good yields by oxidation of the corresponding alcohols using inexpensive and safe oxidants such as phenyliodine (III) diacetate and trichloroisocyanuric acid in the presence of 2,2,6,6-tetramethyl-1-piperidinyloxyl free-radical (