Optimization of polytetrafluoroethylene content in cathode gas diffusion layer by the evaluation of compression effect on the performance of a proton exchange membrane fuel cell

✍ Scribed by Hao-Ming Chang; Chien-Wei Lin; Min-Hsing Chang; Huan-Ruei Shiu; Wen-Chen Chang; Fang-Hei Tsau

• Publisher: Elsevier Science
• Year: 2011
• Tongue: English
• Weight: 719 KB
• Volume: 196
• Category: Article
• ISSN: 0378-7753
• DOI: 10.1016/j.jpowsour.2010.12.090

✦ Synopsis

This research investigates the optimal polytetrafluoroethylene (PTFE) content in the cathode gas diffusion layer (GDL) by evaluating the effect of compression on the performance of a proton exchange membrane (PEM) fuel cell. A special test fixture is designed to control the compression ratio, and thus the effect of compression on cell performance can be measured in situ. GDLs with and without a microporous layer (MPL) coating are considered. Electrochemical impedance spectroscopy (EIS) is used to diagnose the variations in ohmic resistance, charge transfer resistance and mass transport resistance with compression ratio. The results show that the optimal PTFE content, at which the maximum peak power density occurs, is about 5 wt% with a compression ratio of 30% for a GDL without an MPL coating. For a GDL with an MPL coating, the optimal PTFE content in the MPL is found to be 30% at a compression ratio of 30%.