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Optimization of olefin copolymerization: effects of reaction parameters on catalytic activity and properties

✍ Scribed by Ricardo Baumhardt-Neto; Griselda B. Galland; Raquel S. Mauler; Raul Quijada

Book ID
106002300
Publisher
Springer
Year
1998
Tongue
English
Weight
261 KB
Volume
40
Category
Article
ISSN
0170-0839

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Isomerization reaction of hex-1-ene, 1,5-hexadiene and 1,7-octadiene, catalyzed by HRh( CO) (PPh,), and HRh( PPh3)4 at 40Β°C have been studied. Hex-I-ene undergoes total conversion to hex-2-ene at presence of both of catalysts used, whereas isomerization of dienes is catalysed by HRh( CO) ( PPh3), co