𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Optimization of Click Chemistry of Ferrocene Derivatives on Acetylene-Functionalized Silicon(100) Surfaces

✍ Scribed by Simone Ciampi; Guillaume Le Saux; Jason B. Harper; J. Justin Gooding

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
255 KB
Volume
20
Category
Article
ISSN
1040-0397

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The optimization of the reaction conditions for copper‐catalyzed azide‐alkyne ‘click’ cyclo‐addition reactions used to covalently confine substituted ferrocene derivatives on passivated silicon(100) surfaces is reported. Variations in the observed reaction yields and the extent of surface contamination as a function of the source of the copper catalyst and the solvent system used in the ‘click’ procedure were evaluated spectroscopically. The electronic communication between the ferrocene centre and the underlying semiconductor surface was investigated by means of cyclic voltammetry and found to be consistent with that expected for a well‐behaved and robust redox interface.

📜 SIMILAR VOLUMES

ChemInform Abstract: Organometallic Chem
ChemInform Abstract: Organometallic Chemistry on Silicon Surfaces: Formation of Functional Monolayers Bound Through Si—C Bonds
✍ Jillian M. Buriak 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 25 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v