Replacing the 3- and 3''-protons of the ligand 2,6-di(pyrazol-1-yl)pyridine L by mesityl groups changes the electronic ground state of [Cu(L) ] complexes from {d x 2-y 2} to {d z 2} . This is the best example so far for a "homoleptic" Jahn-Teller-compressed six-coordinate Cu complex.
✦ LIBER ✦
Optimal control of the initiation of a pericyclic reaction in the electronic ground state#
✍ Scribed by TIMM BREDTMANN, JÖRN MANZ
- Book ID
- 113094149
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 305 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0253-4134
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