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Optically activeα-chlorooxirans obtained by Darzen's reaction and their absolute configuration

✍ Scribed by V. A. Mamedov; S. Tsuboi; A. T. Gubaidullin; I. A. Litvinov; Ya. A. Levin

Book ID: 105528224
Publisher: Springer US
Year: 1998
Tongue: English
Weight: 99 KB
Volume: 34
Category: Article
ISSN: 0009-3122
DOI: 10.1007/bf02290894

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Benzyl dialkyl phosphates are deprotonated enantioselec-up to 50%. The pro-(S) hydrogen is removed by amides hatively by homochiral lithium amides of isopropyl( 1-phenyl-ving (S) configuration. Homochiral diethyl (S)-phenyl[D+ ethy1)amine or bis(1-phenylethy1)amine. The short-lived ben-methyl phosph